利用激光熔覆技术在45钢表面制备出不同成分配制的原位自生镍基金属陶瓷复合涂层,涂层表面质量良好。涂层在连续变温条件下高温氧化动力学分析表明,涂层成分不同时,稳定氧化阶段持续时间及剧烈氧化速度均有一定差异。此外,不同成分涂层高温氧化后,氧化层表面形貌、质量及氧化物尺寸、分布均有差别。总体来看,激光熔覆表面处理大大提高了材料表面的高温氧化抗力。
Abstract
In-situ synthesized Ni-base metal-ceramic composite coatings with different proportion of composition were fabricated on 45 steel surface by laser cladding. The main ceramic phase was TiB2 in the coating and its surface quality was fairly good. Analysis of high temperature oxidation kinetics of the coatings in continuous changing temperature showed that the stable oxidation remaining time and the violent oxidation speed was a certain different from each other as the coating composition changing. In addition, the surface morphology quality, size and distribution of the oxide production were different from each other as a result of the changing of the coating composition. In general, the high temperature oxidation resistance of the material surface improved greatly through laser cladding surface modification.
关键词
激光熔覆 /
涂层 /
连续变温 /
高温氧化
{{custom_keyword}} /
Key words
laser cladding /
coating /
continuous temperatu /
high temperature oxi
{{custom_keyword}} /
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
YANG San,ZHONG Min-lin,LIU Wen-jin.Study of in-situ TiC particle reinforced Ni-based alloy composite coatings produced by laser cladding[J]. Journal of Aeronautical Materials, 2002, 22(1):26-29.
BARNES S,TIMMS N,BRYDEN B,et al.High power diode laser cladding[J].Journal of Materials Processing Technology, 2003,138:411-416.
KATHURIA Y P.Nd-YAG laser cladding of CrC and TiC cermets[J].Surface and Coatings Technology, 2001,140: 195-199.
ZHANG Wei-ping,LIU Shuo,MA Yu-tao.Study of in-situ synthesis of TiB2 by laser cladding and its microstructure[J].Journal of Dalian University of Technology, 2004, 44(3):402-406.
ZHANG Wei-ping,LIU Shuo,JI Shou-hua,et al.Research on behavior of grain refinement in metal-ceramic surface fine composite coating by laser cladding[J]. Journal of Materials Engineering, 2004, 255(8):12-16.
SOLAK N,USTEL F,URGEN M,et al.Oxidation behavior of molybdenum nitride coatings[J].Surface and Coatings Technology, 2003,174-175:713-719.
LIU Hai-ping,WANG Xiao-hong,HAO Shan-shan,et al. Oxidation of Ti60 alloy and its protection by NiCrAlY coating[J].Journal of Materials Engineering,1998(7): 18-20.
SWAPNIl V SHAH, NARENDRA B DAHOTRE.Laser surface-engineered vanadium carbide coating for extended die life[J].Journal of Materials Processing Technology, 200,124(2):105-112.
WU Y N,ZHANG G,FENG Z C,et al.Oxidation behavior of laser remelted plasma sprayed NiCrAlY and NiCrAlY-Al2O3 coatings[J].Surface and Coatings Technology, 2001,138:56-60.
WANG Yu-lin,SHEN De-jiu,LIAO Bo,et al.Effect of rare earth on Ni-base spontaneous melting alloy by laser cladding[J].Applied Laser, 2003, 23(3):139-141.
WEHNER A,JELIAZOVA Y,FRANCHY R.Growth and oxidation of a Ni3Al alloy on Ni (100) [J].Surface Science, 2003,531:287-294.
{{custom_fnGroup.title_cn}}
脚注
{{custom_fn.content}}
基金
国家自然科学基金资助项目(59701001)
{{custom_fund}}